Liverpool took the lead in the first half through captain Steven Gerrard after he was brought down in the box and went on to convert his penalty beyond Angoy in the Barcelona goal.
Roger Garcia scored the equaliser for the away side on the stroke of half-time after being slipped in by Javier Saviola to finish beyond Sander Westerveld. Rivaldo then converted from the spot after Phil Babb committed a foul in the area.
The Brazilian legend said: "Amazing feeling to be here again at Anfield. One of the greatest stadiums in the world."
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